PREMISE 75 WP
001 01/29/96 PREMISE 75 WP
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SECTION I PRODUCT IDENTIFICATION
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PRODUCT NAME: PREMISE 75 WP
MSDS #: P17367VS
DATE ISSUED: 02/22/95
ISSUED BY: 009711
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PRODUCT NAME........ : PREMISE 75 WP
PRODUCT CODE........ : 216711
EPA REGISTRATION NO.: 3125-455
CHEMICAL FAMILY..... : Chloronicotinyl
CHEMICAL NAME....... : 1-((6-chloro-3-pyridinyl)methyl)l-N-nitro-2-
imidazolidinimine
SYNONYMS............... : Imidacloprid; BAY NTN 33893
FORMULA................ : C9 H10 Cl N5 02
II. HAZARDOUS INGREDIENTS:
INGREDIENT NAME
NUMBER EXPOSURE LIMITS CONCENTRATION (%)
Imidacloprid
138261-41-3 OSHA : Not Established 75 %
ACGIH: Not Established
Ingredient 1968
Specific chemical identity is withheld as a trade secret.
OSHA : Not Established 1-5
ACGIH: Not Established
Ingredient 1611
Specific chemical identity is withheld as a trade secret.
OSHA Not Established 10-20
ACGIH: Not Established
III. PHYSICAL PROPERTIES:
PHYSICAL FORM............. : Powder; Solid
COLOR..................... : Light brown
ODOR: None
MOLECULAR WEIGHT.......... 255.7 (for imidacloprid)
pH....................... 1% Slurry pH 6-8
BOILING POINT........... Not established
MELTING/FREEZING POINT.... Melting: 120-134 C (for imidacloprid)
SOLUBILITY IN WATER...... 9-10% of the mixture
SOLUBILITY (NON AQUEOUS)..: Much of the mixture is soluble in acetone,
SPECIFIC GRAVITY......... methylene chloride and DMF.
BULK DENSITY............ Not established
% VOLATILE BY VOLUME...... Tapped bulk density is approximately 30 lbs/cu-ft
% VOLATILE BY WEIGHT...... Not applicable
EVAPORATION RATE......... 1.5 x 10 -9 mm @ 20 C (for imidacloprid)
VAPOR PRESSURE........... 1.5 x 10 -9 mm @ 20 C (for imidacloprid)
Not established (Butyl acetate = 1)
VAPOR DENSITY............ Not established (Air = 1)
NITROGEN CONTENT......... Approximately 20%
IV. FIRE AND EXPLOSION DATA:
FLASH POINT Not Applicable
EXTINGUISHING MEDIA...........Water; Carbon Dioxide; Dry Chemical;
Foam
SPECIAL FIRE FIGHTING PROCEDURES: Keep out of smoke, cool exposed containers
with water spray. Fight fire from upwind position. Use self-contained
breathing equipment. Contain run-off by diking to prevent entry into
sewers or waterways. Equipment or materials involved in pesticide fires
may become contaminated.
V. HUMAN HEALTH DATA:
ROUTE(S) OF ENTRY....... : Inhalation; Skin Contact; Skin Absorption
HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE:
ACUTE EFFECTS OF EXPOSURE..... : No specific symptoms of acute overexposure
are known to occur in humans. Animal studies have shown that this material
is mildly toxic by the oral and dermal routes. It is minimally irritating
to the conjunctiva of the eye but the irritation is reversible within 24
hours. It is a slight dermal irritant, but is not a dermal sensitizer.
CHRONIC EFFECTS OF EXPOSURE... : No specific symptoms of chronic
overexposure are known to occur in humans.
CARCINOGENICITY............... : This product is not listed by NTP, IARC or
regulated as a carcinogen by OSHA.
MEDICAL CONDITIONS
AGGRAVATED BY EXPOSURE...... : No specific medical conditions are known
which may be aggravated by exposure to this product.
VI. EMERGENCY AND FIRST AID PROCEDURES:
FIRST AID FOR EYES.. : Hold eyelids open and flush with copious amounts of
water for 15 minutes. Call a physician if irritation persists or develops
after flushing.
FIRST AID FOR SKIN. : Remove contaminated clothing. Wash skin with soap
and water. Get medical attention if irritation persists. If signs of
intoxication (poisoning) occur, get medical attention immediately.
FIRST AID FOR INHALATION: First, remove victim to fresh air or uncontaminated
area. If not breathing, give artificial respiration, preferably
mouth-to-mouth. Get medical attention as soon as possible.
FIRST AID FOR INGESTION.: If ingestion is suspected, call a physician or
poison control center. Drink one or two glasses of water and induce vomiting
by touching back of throat with finger, or, if available, by administering
syrup of ipecac. If syrup of ipecac is available, administer 1
tablespoonful (15 mL) of syrup of ipecac followed by 1 to 2 glasses of
water. If vomiting does not occur within 20 minutes, repeat the dose once.
Do not induce vomiting or give anything by mouth to an unconscious person.
NOTE TO PHYSICIAN....... : Treat symptomatically. ANTIDOTES: None
VII EMPLOYEE PROTECTION RECOMMENDATIONS:
EYE PROTECTION REQUIREMENTS........ : Goggles should be used when needed to
prevent dust from getting into the eyes.
SKIN PROTECTION REQUIREMENTS. Wear long sleeves and trousers to prevent
skin contact.
HAND PROTECTION REQUIREMENTS....... The use of chemical-resistant
Gloves to prevent skin contact is recommended as good practice.
RESPIRATOR REQUIREMENTS............ : Under normal handling conditions, no
respiratory protection is needed; however, when potential exposure to
product dust is excessive, wear a NIOSH-approved respirator for dusts and
mists or for pesticides.
VENTILATION REQUIREMENTS........... : Control exposure levels through
the use of general and local exhaust ventilation where needed.
ADDITIONAL PROTECTIVE MEASURES..... : Clean water should be
available for washing in case of eye or skin contamination. Educate and
train employees in safe use of the product. Follow all label instructions.
Launder clothing after use. Wash thoroughly after handling.
VIII. REACTIVITY DATA:
STABILITY...... ...... This is a stable material.
HAZARDOUS POLYMERIZATION... Will not occur.
INCOMPATIBILITIES............ None known
INSTABILITY CONDITIONS.. Strong exothermal reaction above 200 C (for
imidacloprid)
DECOMPOSITION PRODUCTS Proposed: HC1, HCN, CO, NOx (for imidacloprid)
IX. SPILL AND LEAK PROCEDURES:
SPILL OR LEAK PROCEDURES.... : Isolate area and keep unauthorized people away.
Do not walk through spilled material. Avoid breathing dusts and skin
contact. Avoid generating dust (a fine water spray mist, plastic film
cover, or floor sweeping compound may be used if necessary). Use
recommended protective equipment while carefully sweeping up spilled
material. Place in covered container for reuse or disposal. Scrub
contaminated area with soap and water. Rinse with water. Use dry
absorbent material such as clay granules to absorb and collect wash
solution for proper disposal. Contaminated soil may have to be removed and
disposed. Do not allow material to enter streams, sewers, or other
waterways.
WASTE DISPOSAL METHOD: Follow container label instructions for disposal
of wastes generated during use in compliance with the product label. In
other situations, bury in an EPA approved landfill or burn in an
incinerator approved for pesticide destruction. Do not reuse container.
X SPECIAL PRECAUTIONS & STORAGE DATA:
STORAGE TEMPERATURE(MIN/MAX): None/30 day average not to exceed 100 F
SHELF LIFE.................. Not noted
SPECIAL SENSITIVITY......... Not noted
HANDLING/STORAGE PRECAUTIONS: Store in a cool dry area designated specifically
for pesticides. Do not store near any material intended for use or
consumption by humans or animals.
XI. SHIPPING INFORMATION:
Imidacloprid
Insecticides, NOI-NMFC 102120
For emergency assistance involving chemicals,
call CHEMTREC - (800)
424-9300
Vopak USA
6100 Carillon Point, Kirkland WA 98033 - (425)
889-3400
Vopak USA expressly disclaims all express or implied warranties of
merchantability and fitness for a particular purpose, with respect to the
product or information provided herein, and shall under no circumstances be
liable for incidental or consequential damages.
All information appearing
herien is based upon data obtained from the manufacturer and/or recognized
technical sources. While the information is believed to be accurate, Vopak USA
makes no representations as to its accuracy or suffiency. Conditions of use are
beyond Vopak USA's control and therefore users are responsible to verify this
data under their own operating conditions to determine whether the product is
suitable for their particular purposes and they assume all risks of their use,
handling, and disposal of the product, or from the publication or use of, or
reliance upon, information contained herein. This information relates only to
the product designated herein, and does not relate to its use in combination
with any other material or in any other process.