001 11/26/97 PRESSURIZED CONTACT INSECTICIDE
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PRODUCT IDENTIFICATION
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PRODUCT NAME: PRESSURIZED CONTACT INSECTICIDE
MSDS#: P19949VS
DATE ISSUED: 6/16/97
SUPERSEDES: NEW
ISSUED BY: 009118
800 424-9300 CHEMTREC
Formula 1
EPA REG. NO,: 499-444
ACGIH ACGIH OSHA
Active Ingredients: TLV/TWA STEL PEL OTHER
Pyrethrins: 0.5% 5mg/m3 10mg/m3 NE
(CAS 8003-34-7)
Piperonyl Butoxide, NE NE NE
Technical: 4%.
(CAS 51-03-6)
Solvents & Propellants: 95.5%
Acetone (CAS 67-64-1) 750ppm 1000ppm 750ppm 250 ppm NIOSH 10HR TWA
Isoparaffinic NE NE 500PPM
Petroleum Solvent:
(CAS 64742-48-9)
Isopropanol:(CAS 67-63-0) 400PPM 500PPM 400PPM 15MIN CEILING 800 PPM NIOSH
Propane: (CAS 74-98-6)
1000ppm NE NE
All components of this product are listed or excluded from listing on the US
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
SECTION 2: PHYSICAL DATA
Boiling Point: NA
Specific Gravity (Hz0 = 1): 0.80 g/ml at 20 C
Vapor Pressure in Aerosol Can: NA End Use product
Percent Volatile: -95.5%
Vapor Deasily: NE
Evaporation Rate: NA
Solubility In Water: Soluble
Appearance and Odor Sprays as a coarse
spray with characteristic Pyrethrin/Acetone
odor.
SECTION 3. FIRE AND EXPLOSION HAZARD DATA
Flashpoint: Aerosol concentrate -4 F TCC
Flammable Llmits: (Acetone) LEL = 2.5%; UEL = 13%
NFPA 30B Flammability: Level 3 Aerosol
Extinguishing Media: CO2; Dry Chemical; Foam
Special Firetighting Procedures: None required.
Unusual Fire and Explosion Hazards: Contents under pressure. Exposure to
temperatures above 130'F may cause bursting.
Threshold Limit Value: NE
Routes of Entry:
Inhalation?
Secondary
Skin? Ingestion?
Primary Tertiary
Health Hazard (Acute and Chronic) - Signs and Symptoms of Exposure:
Eye: Product may produce eye irritation. Avoid contact with eyes. Product did
not produce any conjunctival irritation, nor was any corneal opacity or iritis
observed (rabbits).
Skin: Prolonged exposure may cause skin irritation. Avoid contact with skin.
Acute Dermal
Toxicity - LD50 > 2,000mg/kg. Does not appear to be a dermal sensitizer to
guinea pigs.
Primary Skin Irritation = 0.13 (rabbits).
Ingestion & Inhalation: Unlikely due to the product being pressurized and
producing particles large enough not to be respirable.
Acute Oral Toxicity - LD50 > 5,000mg/kg.;
Acute Inhalation Toxicity - LC50 > 4.53 mg/L;
Carcinogenicity:
NTP? IARC Monograph? OSHA Regulated?
No No No
Emergency and First Aid Procedures:
If Swallowed: Call a physician or poison control center. Do not induce
vomiting. Do not give anything by mouth to an unconscious person. Avoid
alcohol.
If on Skin: Wash with plenty of soap and water. Get medical attention if
irritation persists.
If in Eyes: Flush with plenty of water. Call a physician if irritation
persists.
If Inhaled: Remove victim to fresh air. It not breathing, give artificial
respiration, preferably mouth-to-mouth. Get medical attention.
Note to Physician: May pose an aspiration pneumonia hazard.
Medical Conditions Generalhy Aggravated by Exposure: None known.
SECTION 5: REACTIVITY DATA
Stability: Indefinite when used according to label directions.
Conditions to Avoid: Do not spray into open flame or onto very hot surfaces.
Hazardous Decomposition Products: Thermal decomposition in open flame will
result in carbon dioxide and carbon monoxide.
Hazardous Polymerization: Will not occur.
Steps to be taken In case material is released or spilled:
If container begins to leak (through puncture, etc.), allow to discharge
completely in well ventilated area, then dispose in safe place. In case of
spillage on skin, wash thoroughly with soap and water.
Emergency Telephone Number of Chemtrec: (800) 424-9300
(for transportation spills)
Waste Disposal Methhod: Pesticide Disposal: Waste resulting from use of this
product may be disposed of on site or at an approved waste disposal facility.
Container Disposal: This container may be recycled in the few but growing
number of communities where steel aerosol can recycling is available. Before
offering for recycling, empty the can by using the product
according to the label (DO NOT PUNCTURE!). If recycling is unavailable, wrap
the container and discard in the trash.
In case of spillage this product is subject to reporting requirements of the
Comprehensive Environmental Response, Compensation, and Liability Act
(CERCLA).
.
SECTION 7. SPECIAL PROTECTION INFORMATION
Respiratory Protection: Notice to Applicator - For prolonged exposure
indoors.wear a Dust Mist filtering respirator (MSHA/NIOSH approval number
prefix TC-21 C).
Ventilation:
Local Exhaust: None required. Mechanical: Provide adequate ventilation of
treatment area.
Special: None required. Other: None required.
Protective Gloves: None required - avoid contact with skin.
Eye Protectlon: None required - avoid contact with eyes.
Other Protective Equlpment: None required.
SECTION 8: SPECIAL PRECAUTIONS
Precautions to be Taken in handling and storage: Keep out of reach of
children. Caution: Harmful if absorbed through skin. Avoid contact with eyes,
skin or clothing. Wash thoroughly with soap and water after handling.
Environmental/Hazards.
This product is toxic to fish. Do
not apply directly to water or to areas where surface water is present or to
intertidal areas below the mean high water mark. Do not contaminate water by
cleaning of equipment or disposal of equipment washwaters.
Physical/ or Chemical Hazards
Extremely Flammable.
Contents under pressure. Keep away from tire, sparks and heated surfaces. Do
not puncture or incinerate container. Exposure to temperatures above 130 F may
cause bursting.
Storage:
Store in a cool area away from heat or open flame.
Other Precautions: Do not spray on plastic, painted, or varnished surfaces or
directly into any electronic equipment such as radios, televisions, computers,
etc. Product should only be used when can temperature is above 60 F. If can
temperature is below 60 F, store at room
temperature until a temperature above 60 F is reached.
SECTION 9: HEALTH RATING INFORMATION
Health -1 Flammability - 3 Reactivity - 2
SECTION 10: SARA TITLE III/SEC. 313 SUPPLIER NOTIFICATION
This product contains the following toxic chemicals subject to the reporting
requirements of section 313 of the emergency planning and community right-to-
know act of 1986 and of 40 CFR 372:
CAS: Chemical Name % by weight
51-03-6 Piperonyl butoxide . 4.0
67-64-1 Acetone 62.0
Proper Shipping Name: Consumer Commodity
Hazard Class: ORM-D
NA - Not Applicable
NE - Not Established
PEL - Permissible Exposure Limit
ACL - Acceptable Ceiling Level
MPC - Maximum Peak Concentration